Abstract
Reaction integration is one of the efficient synthetic methods for preparation of polycyclic aromatic compounds with diverse functionalities. Among these, utilization of the highly reactive molecules as a reactive platform is powerful and straightforward tool for the rapid assembly of polycycles, as selective activation of the starting material under thermodynamic or kinetic control leads to the selective generation of the reactive species, allowing the selective construction of complex structures. In this chapter, organic synthetic reactions of reactive molecules in consideration of kinetic or thermodynamic control are summarized based on a recent progress of our synthetic approach to polyfunctionalized aromatic compounds.
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