Abstract

Porous coordination polymers have intriguing features for instance adaptable surface chemistry, tunable functionalities, a massive surface area, and uniform pore size. Crystal engineering approaches enable the orderly construction of open-framework structures with a wide variety of modulable pore sizes and functions utilizing various organic ligands such as phosphane, cyano groups, and so on. The coordination bond, on the other hand, is strong enough to generate durable materials as well as excellent electrical and magnetic interactions between metal centers.

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