Abstract
Abstract Lithification of a sediment to form a rock may involve cementation, diagenetic reactions, or compaction under load. In these experiments, convex halite lenses were pressed against fiat halite plates at 50° C in a specially designed microscope stage. A saturated brine surrounded the samples, which were observed during the experiment in transmitted and reflected light. No time-dependent convergence was observed between the two crystals, even at mean normal stresses of up to 14 M Pa at the contact. In all experiments, however, the contact (or neck) between the two crystals grew with time as material dissolved from the surrounding lens surfaces, diffused through the pore fluid, and precipitated at the neck. Neck growth rates did not appear to correlate with the applied load, but did systematically increase as the misorientation between the two crystals decreased. Our analysis of the shapes of fluid inclusions formed along the grain boundary within the neck suggests that the grain boundary energy is about 1.8 times greater than the fluid-solid interfacial energy. Neck growth appears to be driven by the reduction of interfacial energy rather than by mechanical loads. Assuming that the interfacial energy is isotropic, and incorporating some geometric simplifications, two models of neck growth were formulated. The rate-controlling steps in the models were either precipitation or diffusion in the pore fluid. The data fit either model equally well. Both models predict that neck growth rate will be rapid at first but will decrease with time, as was observed. Neck growth will lead to an increase in real area of contact between grains in a granular aggregate even without the introduction of supersaturated solutions and may be important in the induration of sediments and the strengthening of fault gouge.
Published Version
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