Abstract
Within the field of polyoxometalate (POM) research, there is a selection of structures that frequently recur due to their stability and reproducibility. These classic POMs may not only form with a variety of addenda atoms and heteroatoms but also they and their derivatives are the substructures of the majority of the larger polyoxometalates. This section will give a brief overview of some of these POMs such as isopolyaions, heteropolyanions, and giant polyoxometalate and the features of polyoxometalates described in a later section.
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