Chaotic classical and half-classical adiabatic reactions: geometric magnetism and deterministic friction

Abstract

We study the dynamics of a heavy (slow) classical system coupled, through its position, to a classical or quantal light (fast) system, and derive the first-order velocity-dependent corrections to the lowest adiabatic approximation for the reaction force on the slow system. If the fast dynamics is classical and chaotic, there are two such first-order forces, corresponding to the antisymmetric and symmetric parts of a tensor given by the time integral of the force–force correlation function of the fast motion for frozen slow coordinates. The antisymmetric part is geometric magnetism, in which the ‘magnetic field’ is the classical limit of the 2-form generating the quantum geometric phase. The symmetric part is deterministic friction, dissipating slow energy into the fast chaos; previously found by Wilkinson, this involves the same correlation function as governs the fluctuations and drift of the adiabatic invariant. In the ‘half-classical’ case where the fast system is quantal with a discrete spectrum of adiabatic states, the only first-order slow force is geometric magnetism; there is no friction. This discordance between classical and quantal fast motion is explained in terms of the clash between the semiclassical and adiabatic limits. A generalization of the classical case is given, where the slow velocity, as well as position, is coupled to the fast motion; to first order, the symplectic form in the lowest-order hamiltonian dynamics is modified.