Changes in the new particle formation and shrinkage events of the atmospheric ions during the COVID-19 lockdown

Abstract

Impacts of environmental changes at Pune, India during the lockdown period imposed due to the Covid-19 pandemic, on the characteristics of the atmospheric ions and the new particle formation (i.e. the formation of molecular clusters and their subsequent growth to larger sizes) and shrinkage events have been investigated. The increase in the small and big cluster ion concentrations and the decrease in intermediate ion concentrations observed during the lockdown period have been associated with the decrease in the aerosols and precursor gases, respectively. During the NPF events, the nucleation mode particles of both polarities grow in size. However, during the unique shrinkage events observed here, particles increase in concentration but do not grow in size during the morning-to-noon period and shrink in the noon-to-evening period during the lockdown period. Simultaneously, the concentration of particles of >25 nm decrease i during the morning hours and increase during the afternoon hours .On the shrinkage event days, solar irradiance is higher and relative humidity is lower throughout the day than on the NPF/no-event days. Occurrence of shrinkage events has been proposed to be associated with the change in saturation vapour pressure of different chemical species with temperature/solar irradiance.