Changes in Microstructure and Mechanical Properties of Goryeo Dynasty Bronze Vessels with Manufacturing Process

Abstract

Bronze vessels are manufactured using casting and forging techniques, and various microstructures can be observed depending on the manufacturing process. In this study, we confirmed mechanical properties and microstructural evolution in the manufacturing process by observing the microstructures and composition analysis of 18 bronze vessels in the Goryeo Dynasty excavated from historical sites. The results show that 13 of the bronze vessels were manufactured using a Cu-Sn alloy with a Sn content of 20 to 24 wt%. The α phase and β(M) phase were observed, indicating that hot forging and quenching treatment were performed after casting. 3 bronze vessels were produced from a Cu-Sn-Pb alloy, and considering that the α phase and α+δ phase were observed, it could be seen that the process was completed by slow cooling after casting. The correlation between the type of bronze vessel and the manufacturing process has not been confirmed, except of ewer. It was confirmed that various microstructures were created depending on the manufacturing process and that the mechanical properties also changed. Bronze vessels composed of the α phase and α+δ phase due to the casting process had lower Vickers hardness values compared to bronze vessels that showed the quenched β(M) or γ phase. Electron backscatter diffraction (EBSD) phase analysis and kernel average misorientation (KAM) were performed using six bronze vessels composed of α and β(M) phases. The results showed that the factors affecting hardness were the ratio of the β(M) phase and the KAM value. However, it could not be confirmed to what extent the ratio of the β(M) phase and KAM value affected the improvement in mechanical properties.