Change in the structure of poly(tetramethylene succinate) under tensile stress monitored with solid state 13C NMR

Abstract

A new solid-state NMR experimental equipment was developed to monitor the structural change of polymer and protein fibers under active uniaxial deformation. The equipment was applied to monitoring change in the structure of a biodegradable aliphatic polyester fiber, poly(tetramethylene succinate) (PTMS; [–O(CH2)4OCO–(CH2)2CO–]n), as a function of tensile stress. The crystal transition from α to β forms for PTMS was induced by stress and monitored by the change of the methylene region in the 13C NMR spectra. The 13C chemical shielding constant for the model compound of poly(tetramethylene succinate) was calculated using the GIAO–CHF (gauge invariant atomic orbitals–coupled Hartree–Fock) with ab initio 6-311G∗∗ basis set. This calculation acceptably explains the experimental results.