Change in characteristics of water-soluble and water-insoluble brown carbon aerosols during a large-scale biomass burning.

Abstract

Light-absorbing organic aerosol (brown carbon (BrC)) can significantly affect Earth's radiation budget and hydrological cycle. Biomass burning (BB) is among the major sources of atmospheric BrC. In this study, day/night pair (10-h integrated) of ambient PM2.5 were sampled every day before (defined as T1, n = 21), during (T2, n = 36), and after (T3, n = 8) a large-scale paddy-residue burning during October-November over Patiala (30.2° N, 76.3° E, 250m amsl), a site located in the northwestern Indo-Gangetic Plain (IGP). PM2.5 concentration varied from ~ 90 to 500μgm-3 (average ± 1σ standard deviation 230 ± 114) with the average values of 154 ± 57, 271 ± 122, and 156 ± 18μgm-3 during T1, T2, and T3 periods, respectively, indicating the influence of BB emissions on ambient air quality. The absorption coefficient of BrC (babs) is calculated from the high-resolution absorption spectra of water-soluble and methanol-soluble organic carbon measured at 300 to 700nm, and that at 365nm (babs_365) is used as a general measure of BrC. The babs_365_Water and babs_365_Methanol ranged ~ 2 to 112Mm-1 (avg 37 ± 27) and ~ 3 to 457Mm-1 (avg 121 ± 108), respectively, suggesting a considerable presence of water-insoluble BrC. Contrasting differences were also observed in the daytime and nighttime values of babs_365_Water and babs_365_Methanol. Further, the levoglucosan showed a strong correlation with K+ (slope = 0.89 ± 0.06, R = 0.92) during the T2 period. We propose that this slope (~ 0.9) can be used as a typical characteristics of the emissions from paddy-residue burning over the IGP. Absorption Ångström exponent (AAE) showed a clear day/night variability during the T2 period, and lower AAEMethanol compared to AAEWater throughout the sampling period. Further at 365nm, average relative atmospheric radiative forcing (RRF) for BrCWater is estimated to be ~ 17%, whereas that of BrCMethanol ~ 62%with respect to elemental carbon, suggesting that BrC radiative forcing could be largely underestimated by studies those use BrCWater only as a surrogate of total BrC.