Abstract
Reported here is a photocatalytic strategy for Ritter‐type C‐H amination of alkylarenes with nitriles. Under the irradiation of blue light and the catalysis of a simple Ce(III) salt, alkylarenes were brominated by CBr3COOH and thereby channeled to the normal Ritter pathway to afford amide products. A wide range of alkylarenes and nitriles were tolerated, with a few equivalents of a nitrile being feasible.
Published Version
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