[Ce3+-Pr3+-Nd3+]:CsPbI2.2Br0.8 stable energy system for photonic and electrical performance upgradation in multitudinous applications

Abstract

Adopting an integrated and consolidated strategy to energy generation, conversion, and storage is linked to energy sustainability in the modern day. Current investigation explores the lanthanide triple doping mechanism coupled with temperature optimization using (cerium, praseodymium, and neodymium)-oxide to modify CsPbI2.2Br0.8 forming the stable [Ce3+-Pr3+-Nd3+]:CsPbI2.2Br0.8 (CPN:CPVSK) hetero-system. CPN:CPVSK thin films have remarkable optical output for the prolonged duration of 28 days with the band gap energy spanning around 1.64–1.67 eV. These thin films have cubic phase with the 65.44 nm average crystallite size and these thin films have excellent surficial binding without any holes or cracks. CPN:CPVSK was employed as an active light trapping material inside perovskite solar cells processed and analyzed at ambient conditions. The temperature increment from 100 to 200 °C subsequently lead to improvement in efficiency from 6.91% to 15.5% with considerable improvement in fill factor. CPN:CPVSK effectively generated pure H2 with the minor overpotential and Tafel slope values of 132 mV and 122.3 mV dec−1 while the O2 production activity was unappreciable. CPN:CPVSK is a potential material for battery application with the excellent unit capacity of 354 mA H g−1 and lower Rs of 0.44 Ω. Rare earth doped perovskite material is a sustainable, cost effective, and facile to prepare with the greater candidature for practical applications.