Abstract

A theoretical model for cavitation in viscoelastic media is developed which incorporates both interfacial and rheological arguments. The properties of interfacial and bulk cavities are correlated, and the influence of time-dependent cavity vapor pressure Pν(t) or hydrostatic tension σ̄(t) are correlated with the extension ratio λ=r/r0 of the cavity surface in a stress relaxation model. Experimental data are analysed for cavitation by peeling, tensile loading of butt joints, and superheating of swollen elastomers. For each case an agreement between theory and experiments is obtained which identifies the specific mode of cavitation and indicates for all cases the presence of prenucleated cavities with radii r0⩾1.0 microns. The direct correlation of peeling stresses with viscoelastic restraints to interfacial cavitation provides a new type of experimental confirmation for the applicability of rate-temperature superposition to peeling data. The implicit assumption that the interfacial failure stress depends upon frequency or strain rate in the same fashion as cohesive failure stress is confirmed by cavitation theory for the general case where surface tension constraints are negligible compared to viscoelastic constraints.

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