Abstract
In the title compound, [Cd2I4(C6H14N2)2]n, there are two independent CdII ions. One CdII ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other CdII ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment. Two of the iodido ligands act as bridging ligands connecting CdII ions and forming a one-dimensional polymer along [010]. In the crystal, N—H⋯I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001).
Highlights
Laboratory of Bioorganic and Medicinal Chemistry, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, People’s Republic of China
The other CdII ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment
Two of the iodido ligands act as bridging ligands connecting CdII ions and forming a one-dimensional polymer along [010]
Summary
In the title compound, [Cd2I4(C6H14N2)2]n, there are two independent CdII ions. One CdII ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other CdII ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment. Two of the iodido ligands act as bridging ligands connecting CdII ions and forming a one-dimensional polymer along [010]. N—H I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001)
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