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Abstract
The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+ and sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O atoms from two carboxylate groups and two water O atoms. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, intermolecular hydrogen bonds between carboxylate O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure. The compound is isotypic with the Zn analog.
Highlights
Sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes
O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure
For related compounds based on 4,40 -sulfonyldibenzoic acid, see: Xiao et al (2007); Wu et al (2007); Miyazawa et al (2009); Wang et al (2009)
Summary
R factor = 0.032; wR factor = 0.102; data-to-parameter ratio = 12.4. The title compound, [Cd(C14H8O6S)(H2O)2]n, comprises zigzag chains parallel to [111] of alternating [Cd(H2O)2]2+. Sulfonyldibenzoate units, with the Cd and S atoms lying on crystallographic twofold axes. The central CdII ion is in a slightly distorted octahedral geometry, coordinated by six O atoms from two carboxylate groups and two water O atoms. An intramolecular C—H O hydrogen bond occurs. O atoms and coordinated water molecules in adjacent chains lead to the formation of a three-dimensional network structure. The compound is isotypic with the Zn analog
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