Abstract
In the title one-dimensional coordination polymer, [Co(C2H3O2)2(C26H18N4)]n, the CoII atom (site symmetry 2) is coordinated by two O,O′-bidentate acetate ions and two 4,4′-bis(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN2O4 octahedral geometry. The bridging ligand, which is completed by crystallographic twofold symmetry, links the CoII atoms into [10] chains. Within the ligand, the dihedral angle between the benzene and benzimidazole rings is 48.31 (8)°.
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