Abstract
In the title one-dimensional coordination polymer, [ZnCl2(C12H10N4)]n, the ZnII atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis(imidazol-1-yl)benzene ligands, generating a distorted tetrahedral ZnCl2N2 geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the ZnII atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82 (13)°.
Highlights
In the title one-dimensional coordination polymer, [ZnCl2(C12H10N4)]n, the ZnII atom is coordinated by two chloride ions and two 1,4-bis(imidazol-1-yl)benzene ligands, generating a distorted tetrahedral ZnCl2N2 geometry for the metal ion
The bridging ligand, which is completed by crystallographic inversion symmetry, links the ZnII atoms into zigzag chains propagating in [101]
Symmetry codes: (i) −x+1, y, −z+1/2; (ii) −x+1/2, −y−1/2, −z
Summary
Republic of China, and cThe Second Hospital of Jilin University, Changchun, Jilin
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