Abstract
The title complex, {(C16H12FN2)[PbI3]}n, consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI3 − anion formed by face-sharing PbI6 octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI3]− fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.
Highlights
The title complex, {(C16H12FN2)[PbI3]}n, consists of 1-[(2fluorobenzylidene)amino]quinolinium cations and a polymeric PbI3À anion formed by face-sharing PbI6 octahedra
One cation and one anionic [PbI3]À fragment are observed in general positions
Polymeric chains are produced by the glide plane perpendicular to the a axis
Summary
ISSN 1600-5368 catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-liodido]] Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.020 A; R factor = 0.047; wR factor = 0.082; data-to-parameter ratio = 19.7. Crystal data (C16H12FN2)[PbI3] Mr = 839.17 Orthorhombic, Pbca a = 20.888 (4) Ab = 7.9112 (15) Ac = 25.197 (5) A
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