Abstract
The title complex, (C6H16N2)[WS4], consists of tetrahedral [WS4]2− dianions and organic dications. There are two crystallographically independent 1,4-dimethylpiperazinium (1,4-dmpH2) dications in the asymmetric unit, both of which are located around a centre of inversion, while the anions are located in general positions. The anions and cations are connected by hydrogen bonding.
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