Abstract
In the title compound, [CdI2(C18H12N6S2)]n, the 4,4′-di-4-pyridyl-2,2′-disulfanediyldipyrimidine (L) ligand bridges two CdII centers, forming polymeric zigzag chains extending along the b axis. The CdII ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetrahedral geometry.
Highlights
In the title compound, [CdI2(C18H12N6S2)]n, the 4,40-di-4pyridyl-2,20-disulfanediyldipyrimidine (L) ligand bridges two CdII centers, forming polymeric zigzag chains extending along the b axis
The CdII ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetrahedral geometry
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV2663)
Summary
ISSN 1600-5368 catena-Poly[[diiodidocadmium(II)]-l4,40-di-4-pyridyl-2,20-disulfanediyldipyrimidine] Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.007 A; R factor = 0.027; wR factor = 0.057; data-to-parameter ratio = 15.4. Crystal data [CdI2(C18H12N6S2)] Mr = 742.69 Triclinic, P1 a = 10.0145 (7) Ab = 10.7294 (8) Ac = 11.7217 (9) A = 93.133 (1) = 109.886 (1)
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