Synthesis, structure and photoluminescence properties of a three-dimensional cadmium(II) (4,5)-connected coordination network.

Abstract

The assembly of coordination polymers from metal ions and organic moieties is currently attracting considerable attention in crystal engineering due to their intriguing architectures and potential applications as functional materials. A new coordination polymer, namely poly[[μ2-trans-1,2-bis(pyridin-3-yl)ethylene-κ2N:N']bis(μ4-4,4'-oxydibenzoato-κ6O:O,O':O'':O'',O''')dicadmium(II)], [Cd2(C14H8O5)2(C12H10N2)]n or [Cd2(4,4'-OBB)2(3,3'-BPE)]n, has been synthesized by the the self-assembly of Cd(NO3)2·4H2O, 4,4'-oxydibenzoic acid (4,4'-H2OBB) and trans-1,2-bis(pyridin-3-yl)ethene (3,3'-BPE) under hydrothermal conditions. The title compound was structurally characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. Each CdII centre is coordinated by six carboxylate O atoms from four different 4,4'-OBB2- ligands and by one pyridyl N atom form a 3,3'-BPE ligand. Adjacent crystallographically equivalent CdII ions are bridged by 4,4'-OBB2- ligands, affording a two-dimensional [Cd(4,4'-OBB)]n net extending in the ac plane. Neighbouring [Cd(4,4'-OBB)]n nets are interlinked by 3,3'-BPE along the b axis to form a three-dimensional (3D) [Cd2(4,4'-OBB)2(3,3'-BPE)]n coordination network. In the network, each CdII centre is linked by four different 4,4'-OBB2- ligands and one 3,3'-BPE ligand. Meanwhile, each 4,4'-OBB2- ligand connects four separate CdII ions. Therefore, if the 4,4'-OBB2- ligands and CdII ions are considered as 4- and 5-connecting nodes, the structure of the title compound can be simplified as a 3D (4,5)-connected binodal framework with the rare (4462)(4466) TCS topology (Pearson, 1985; Blake et al., 2011). The thermal stability and photoluminescence properties of the title compound have also been investigated.