Abstract

The 4,4′-bipyridine spacer in the title compound, [Co(C10H8NO2)2(C10H8N2)(H2O)2]·4H2O, links the diaqua­cobalt(II) dicarboxyl­ate units into a linear chain; the metal atom lies on a center of inversion in an octa­hedral environment. The coordinated and uncoordinated water mol­ecules inter­act through O—H⋯O hydrogen bonds to form a three-dimensional network.

Highlights

  • H atoms treated by a mixture of independent and constrained refinement

  • The 4,40-bipyridine spacer in the title compound, [Co(C10H8NO2)2(C10H8N2)(H2O)2]Á4H2O, links the diaquacobalt(II) dicarboxylate units into a linear chain; the metal atom lies on a center of inversion in an octahedral environment

  • The coordinated and uncoordinated water molecules interact through O—HÁ Á ÁO hydrogen bonds to form a three-dimensional network

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Summary

Structure Reports Online

ISSN 1600-5368 catena-Poly[[[diaquabis(1H-indole-3acetato-jO)cobalt(II)]-l-4,40-bipyridinej2N:N0] tetrahydrate] Key indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.005 A; R factor = 0.040; wR factor = 0.103; data-to-parameter ratio = 11.4. Mr = 671.56 Monoclinic, P21=c a = 11.5011 (3) Ab = 16.0953 (4) Ac = 8.8302 (2) A

Data collection
Related literature
DÁ Á ÁA
Bruker APEXII diffractometer

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