Abstract
In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)2·0.5C10H8N2·H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water molecules. The 4,4′-bipy ligands bridge the ZnII atoms into a chain structure along [100]. The uncoordinated 4,4′-bipy molecule lies on an inversion center. O—H⋯O and O—H⋯N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4′-bipy molecules and the water molecules into tow-dimensional networks.
Highlights
In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)20.5C10H8N2H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,40 bipyridine (4,40 -bipy) ligands, two N atoms from a chelating
The uncoordinated 4,40 -bipy molecule lies on an inversion center
Symmetry codes: (iii) x−1, y, z; (iv) x, y+1, z; (v) −x+1, y+1/2, −z+1/2; (vi) −x+1, y−1/2, −z+1/2
Summary
Refinement a Department of Chemistry, Capital Normal University, Beijing 100048, People’s. Republic of China, and bKey Laboratory of Terahertz Optoelectronics, Ministry of Education, Capital Normal University, Beijing 100048, People’s Republic of China. R factor = 0.048; wR factor = 0.132; data-to-parameter ratio = 12.8. In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)20.5C10H8N2H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,40 bipyridine (4,40 -bipy) ligands, two N atoms from a chelating. 1,10-phenanthroline ligand and two O atoms from two mutually cis water molecules. The 4,40 -bipy ligands bridge the ZnII atoms into a chain structure along [100]. The uncoordinated 4,40 -bipy molecule lies on an inversion center. O—H O and O—H N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,40 bipy molecules and the water molecules into tow-dimensional networks
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