Abstract
The title compound, [Hg5Br10(C7H8N2O)2]n, contains two μ3-bridging Br atoms, six μ2-bridging Br atoms and two terminal Br atoms. One HgII atom, lying on an inversion center, adopts a distorted octahedral geometry defined by six Br atoms. Two HgII atoms adopt a distorted square-pyramidal geometry by five Br atoms and the other two HgII atoms have a distorted tetrahedral geometry by two N atoms from a chelating O-methyl pyridine-2-carboximidate ligand and two Br atoms. The Br atoms link the HgII atoms into a ribbon structure along [100].
Highlights
The title compound, [Hg5Br10(C7H8N2O)2]n, contains two 3bridging Br atoms, six 2-bridging Br atoms and two terminal
One HgII atom, lying on an inversion center, adopts a distorted octahedral geometry defined by six Br atoms
Symmetry codes: (i) x+1, y, z; (ii) −x+1, −y+1, −z
Summary
ISSN 1600-5368 catena-Poly[di-l3-bromido-hexa-l2bromido-dibromidobis(O-methyl pyridine-2-carboximidate-j2N,N0 )pentamercury(II)] Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran, and bDepartment of Chemistry, Faculty of Science, Azarbaijan Shahid Madani
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