Abstract
In the title compound, [Cd(C2N3)2(C3H7NO)2], the Cd2+ ion lies on an inversion center and adopts an octahedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethylformamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010].
Highlights
In the title compound, [Cd(C2N3)2(C3H7NO)2], the Cd2+ ion lies on an inversion center and adopts an octahedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethylformamide O atoms occupy the axial positions
The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010]
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (N–C) = 0.004 A; R factor = 0.022; wR factor = 0.058; data-to-parameter ratio = 14.5. Crystal data [Cd(C2N3)2(C3H7NO)2] Mr = 390.70 Triclinic, P1 a = 6.5325 (13) Ab = 7.6003 (15) Ac = 8.6051 (17) A = 104.28 (3) = 106.90 (3)
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