Abstract
The title compound, {[Zn(C12H8O4)(C5H5N)(H2O)]·C5H5N}n, has been prepared by hydrothermal reaction. The ZnII atom is six-coordinated by four carboxylate O atoms of two p-phenylenediacrylate (ppda2−) ligands, one N atom of a pyridine molecule and one O atom of a water molecule in a distorted octahedral environment. The carboxylate groups of the ppda2− anions are in a bridging–chelating mode, in which two O atoms chelate one Zn2+ ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with intermolecular edge-to-face interactions. Further linkages between the layers through O—H⋯O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture with one-dimensional rectanglar channels.
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.91 e Å3
The ZnII atom is six-coordinated by four carboxylate O atoms of two pphenylenediacrylate ligands, one N atom of a pyridine molecule and one O atom of a water molecule in a distorted octahedral environment
The carboxylate groups of the ppda2 anions are in a bridging–chelating mode, in which two O atoms chelate one Zn2+ ion
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.91 e Å3. The ZnII atom is six-coordinated by four carboxylate O atoms of two pphenylenediacrylate (ppda2) ligands, one N atom of a pyridine molecule and one O atom of a water molecule in a distorted octahedral environment. The carboxylate groups of the ppda anions are in a bridging–chelating mode, in which two O atoms chelate one Zn2+ ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with intermolecular edgeto-face interactions. Further linkages between the layers through O—H O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture with onedimensional rectanglar channels
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
