Abstract
In the title compound, [Cu(C2N3)(C10H8N2S2)]n, the CuI atoms are connected by bridging dicyanamide ligands, forming chains parallel to [100]. Each CuI atom displays a tetrahedral coordination environment, formed by one S atom and three N atoms from one 2-(pyridin-2-yldisulfanyl)pyridine and two dicyanamide ligands. The crystal structure is stabilized by C—H⋯N hydrogen bonds, forming a three-dimensional network.
Highlights
In the title compound, [Cu(C2N3)(C10H8N2S2)]n, the CuI atoms are connected by bridging dicyanamide ligands, forming chains parallel to [100]
The crystal structure is stabilized by C— HÁ Á ÁN hydrogen bonds, forming a three-dimensional network
Symmetry codes: (i) x−1, y, z; (ii) x+1, y, z
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.003 A; R factor = 0.028; wR factor = 0.081; data-to-parameter ratio = 14.7. In the title compound, [Cu(C2N3)(C10H8N2S2)]n, the CuI atoms are connected by bridging dicyanamide ligands, forming chains parallel to [100]. Each CuI atom displays a tetrahedral coordination environment, formed by one S atom and three N atoms from one 2-(pyridin-2-yldisulfanyl)pyridine and two dicyanamide ligands. The crystal structure is stabilized by C— HÁ Á ÁN hydrogen bonds, forming a three-dimensional network. Related literature For potential applications of metal-organic frameworks, see: Eddaoudi et al (2001). For metal-organic frameworks constructed from flexible ligands, see: Xu et al (2009). See: Mal et al (2006); Schlueter et al (2007); Sen et al (2007).
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