Abstract

Abstract The catalytic reduction of CO 2 gas without protonic solvents was demonstrated successfully using a new electrochemical hydrogenation system constructed previously by us. Formic acid was detected as a product of the CO 2 reduction together with H 2 evolution as a by-product. The maximal current efficiency for formic acid production in the present study was about 75%, and it depended on the reaction time and current density for the palladization.

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