Catalytic Conversion of Oil in Model and Natural Reservoir Rocks

Abstract

The catalytic activity of metal oxides in the processes of low- and high-temperature oxidation (LTO and HTO, respectively) of oil was studied on model systems consisting of oil-saturated quartz sand with additives of Al2O3, Cr2O3 and MgO using thermal analysis methods. The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. The cracking reactions lead to a decrease in the content of heteroatoms in resins and asphaltenes.