Abstract
We describe the carbon-carbon coupling of myrcene with methyl acetoacetate in biphasic liquid-liquid systems using neutral and cationic TPPTS- or TPPMS-rhodium complexes. Mechanistic studies based on labelling experiments and the nature of the catalytic precursor were investigated. The influence of chlorine concentration and the major role of the solvent have also been examined. We have shown that TPPMS can advantageously replace TPPTS in industrial process.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
