Abstract
1. In the radical telomerization of vinyl chloride with CCl4, catalyzed by Fe(CO)5, Fe(AA)3 or FeCl3, the yield of the adduct increases when compared with peroxide initiation. The amount of the adduct passes through a maximum when the catalyst concentration is increased. An increase in the relative yield of the higher telomer homologs, as well as a reduction in the telomerization rate, is observed in the presence of Fe(CO)5 or FeCl3 when dilution is with methanol. 2. It was shown that direct reaction of the intermediate or starting chlorine-containing iron compound with electrophilic CCl3(CH2CHCl)n. radicals is possible via the mechanism of ligand transfer.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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