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Abstract
1. The radical telomerization of vinyl chloride by 1,1,1,3-tetrachloropropane and 1,1,1-trichloroethane was studied in the presence of Fe(CO)5 in isopropyl alcohol medium, leading to the formation of compounds with the structure RCH2CCl2 (CH2CHCl)nCl, where R=H, ClCH2. Telomer homologs with n=1–3 were isolated, and their structure demonstrated. 2. Iron pentacarbonyl, in conjunction with isopropyl alcohol, is not only an initiator of this telomerization, but at definite concentrations it participates in chain propagation, changing the yields of the telomer homologs and the particular transfer constants.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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