Abstract

The present review describes several examples of the use of soluble and immobilized complexes of rhodium with pyridine ligands as catalysts. Examples include the water-gas shift reaction, the carbonylation of methanol, the reduction of nitroarenes, the hydrocarboxylation and oligomerization of CO/ethylene, the hydrocarbonylation of 1-hexene, the hydroesterification and hydroformylation–acetalization of 1-hexene, the hydrodechlorination of dichloroethane, the carbonylation of naphtha and the hydrogenation and hydroformylation of alkenes.

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