Abstract

The dependence of the frequency and broadening of optical phonons on the Fermi level is theoretically studied in carbon nanotubes. In metallic nanotubes, the frequency shift exhibits a logarithmic divergence and the broadening vanishes discontinuously when the Fermi level reaches the half of the optical-phonon frequency for the longitudinal mode, while the transverse mode is not affected. In semiconducting nanotubes, the frequency is raised for both transverse and longitudinal modes.

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