Abstract
AbstractCarboxylation of arenes utilizing CO2 into value‐added chemicals has received much attention but remains a challenge. Herein, we report a Ti−Zr oxide catalyst which shows high activity in the carboxylation of toluene with CO2‐derived dimethyl carbonate (DMC) into methyl methylbenzoates, while the individual TiO2 and ZrO2 component show poor catalytic performance. It was found that the excellent performance is related to the amorphous state of the Ti−Zr mixed‐metal oxide which possesses high acidity and moderate basicity together with high specific surface area.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
