Abstract
Study regionThis study focuses on boreal lakes in the Athabasca Oil Sands Region (AOSR), Alberta, Canada between latitude 55.68°N and 59.72°N and longitude 110.02°W and 115.46°W. Study focusThis study focuses on interpretation of hydrochemistry from 50 lakes thought to be acid sensitive, and so monitored by the Regional Aquatic Monitoring Program (RAMP) over the last two decades. This study uses basic statistics, principal component analysis, lithological evidence, CO2 saturation estimates, mineral equilibria and δ13CDIC measurements to describe and assess controls on pH and to investigate causal factors of observed pH increase in the lakes. New hydrological insights for the regionOur assessment provides evidence of two main geochemical processes that control pH increase, namely carbonate dissolution and organic matter uptake, the latter a particularly important component of alkalinity in low pH lakes. Lakes in all subregions show strong evidence of dissolution of marine carbonates of undetermined source, and lake water appears to be trending from CO2 super-saturation towards atmospheric CO2 equilibrium. This supports the hypothesis of carbonate input due to permafrost thaw via surface or groundwater pathways, but also reveals likely influence from CO2 dissolution mechanisms related to climatic influence on ice cover duration.
Published Version
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