Abstract
Coordination of a heterocumulene to a basic metallic center modifies the electronic properties of the former species. Thus, reaction of carbodiimides and metal carbonyl anions at −78°C affords (after treatment with phosgene) isocyanide complexes such as (1) and (after protonation) diaminocarbene complexes such as (2). equation image
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More From: Angewandte Chemie International Edition in English
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