Abstract
Herein we report the design and successful catalytic application of modified Trost -ligands in asymmetric allylic alkylation (AAA) reactions. A small set of carbamate-monophosphine P , O -ligands has been prepared in a straightforward two-step synthetic procedure. After optimization of the reaction conditions, high catalytic activities and excellent enantioselectivity up to >99% have been attained.
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