Car☐ylation of saturated hydrocarbons by gif systems (Fe 0/CO/O 2, and CU 0/CO/O 2 in pyridine-acetic acid)

Derek H.R Barton,Eva Csuhai,Dari´O Doller

doi:10.1016/s0040-4039(00)60091-6

Car☐ylation of saturated hydrocarbons by gif systems (Fe 0/CO/O 2, and CU 0/CO/O 2 in pyridine-acetic acid)

Derek H.R Barton, Eva Csuhai + Show 1 more

https://doi.org/10.1016/s0040-4039(00)60091-6

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Journal: Tetrahedron Letters	Publication Date: Jul 1, 1992
Citations: 12

Affiliation: Texas A&M University

#Gif Systems #Pyridine-acetic Acid + Show 5 more

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Abstract

Saturated hydrocarbons are transformed into the corresponding homologous car☐ylic acid by treatment with Fe 0/CO/O 2 or Cu 0/CO/O 2 in pyridine/acetic acid. Mechanistic studies support a reaction pathway involving the insertion of CO into a carbon-iron or carbon-copper bond.

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