Abstract

A simple of munitions grade tabun, known to contain several impurities, was studied by combined capillary column gas chromatography—mass spectrometry under both electron-impact and chemical ionization conditions. Five impurities, three of which were previously unreported in tabun, were identified and characterized based on their mass spectral data. Ammonia chemical ionization was particularly useful since this technique provided molecular ion information for allthe organophosphorous impurities.

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