Abstract
We report experiments displaying simultaneous measurement of mass-selected delayed pulsed field ionization spectra of two isotopically different species in a common laser focus. The experiments show that charge transfer from a ZEKE excited species into high Rydberg states of surrounding ions although definitely observable is only a minor contribution to typical ZEKE spectra at normal low laser intensities and is below the level if ZEKE fragment spectra from up-pumped Rydbergs are recorded.
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