Abstract

Phase transitions, as the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities. For liquid helium, for example, a divergence of the specific heat signals the transition from the normal fluid to the superfluid state. Apart from liquid helium, determining the specific heat of a Bose gas has proven to be a challenging task, for example, for ultracold atomic Bose gases. Here we examine the thermodynamic behaviour of a trapped two-dimensional photon gas, a system that allows us to spectroscopically determine the specific heat and the entropy of a nearly ideal Bose gas from the classical high temperature to the Bose-condensed quantum regime. The critical behaviour at the phase transition is clearly revealed by a cusp singularity of the specific heat. Regarded as a test of quantum statistical mechanics, our results demonstrate a quantitative agreement with its predictions at the microscopic level.

Highlights

  • Phase transitions, as the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities

  • It has been proposed that superfluid helium forms a macroscopic matter wave as a consequence of Bose–Einstein condensation[3], which describes the condensation of the ideal Bose gas at low temperatures due to quantum statistics[4]

  • Evidence for a non-classical specific heat has been reported[10,11], but the accuracy obtained in experiments with weakly interacting atomic Bose gases has not been sufficient for an unambiguous determination of the temperature dependence of the heat capacity

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Summary

Introduction

As the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities. 2.2 K, liquid helium shows peculiar hydrodynamic properties, such as a flow without viscosity, the fountain effect or the formation of vortices[1] This transition from a normal fluid to a superfluid has been named l-transition, which originates from the fact that plotting the heat capacity versus temperature[2] results in a graph resembling the greek letter l. Soon after this discovery, it has been proposed that superfluid helium forms a macroscopic matter wave as a consequence of Bose–Einstein condensation[3], which describes the condensation of the ideal (interaction-free) Bose gas at low temperatures due to quantum statistics[4]. The observed specific heat shows a cusp singularity, illustrating critical behaviour for a photon gas analogous to the l-transition of liquid helium

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