Abstract
The heats of solution of LiClO 4, LiCl, NaClO 4, NaBPh 4, Co(ClO 4) 2, Ph 4AsCl and Ph 4AsClO 4 were measured in acetonitrile (AN)-dimethylsulfoxide (DMSO) mixtures over the whole range of solvent composition. The heats of transfer of single ions from DMSO to AN-DMSO mixtures were determined, based on the tetraphenylarsonium tetraphenylborate (TATB) assumption. The variation in the ionic heats of transfer with solvent composition is discussed.
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