Abstract
Glass transition is one of the central research issues of ionic liquids (ILs). In particular, the most typical ILs, imidazolium-basedones (ImILs) are readily supercooled and exhibit glass transitions below room temperature. We have measured the heat capacities of several ImILs, encoded as CnmimX (n: alkyl carbon number, n = 2–8, X: anion, X = Cl, I, FeCl4, TFSI) using an adiabatic calorimeter. We found that most of ImILs exhibit glass transitions with large Cp jumps in a temperature range between 170 K and 230 K. The large Cp jumps reflect that these ILs are fragile liquids that exhibit large structural change depending on temperature near the glass transition temperature Tg. It is also revealed that Tg does not depend much on n but on the anion radius. We have investigated the dynamics of CnmimX (n = 2–8, X = Cl, NO3, PF6, TF, FSI, TFSI) by means of a quasielastic neutron scattering (QENS) technique. It was clarified that the ionic diffusion is directly associated with the viscosity and glass transition. The activation energy ΔEa of the ionic diffusion increases with decreasing anion size but remains almost unchanged with n as found for Tg. These systematic change of Tg and ΔEa can be explained well by taking account the nano-domain structure which is the most characteristic feature of ImILs.
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