Abstract
Calculations are carried out for the energy accommodation coefficient at a gas–surface interface using a recently developed classical mechanical theory of atom–surface collisions that includes both direct scattering and trapping–desorption processes in the physisorption well of the interaction potential. Full three-dimensional calculations are compared with the available data for the accommodation of rare gases at a tungsten surface and reasonable agreement is found for the heavier gases for which classical physics is expected to be valid at all measured temperatures.
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