Abstract
Dissolution rates of UO 2 fuel are determined as a function of alpha and gamma dose rates. These room-temperature rates are used to calculate the dissolution rates of used fuel at 100°C. Also, the alpha, beta and gamma dose rates in water in contact with the reference used fuel are calculated as a function of cooling time. These results are used to calculate used CANDU fuel dissolution rates as a function of time since emplacement in a defective copper container for the Canadian Nuclear Fuel Waste Management Program. It is shown that beta radiolysis of water is the main cause of oxidation of used CANDU fuel in a failed container and that the use of a corrosion model is required for ~1000 a of emplacement in the waste vault. The results obtained here can be adopted to calculate used nuclear fuel dissolution rates for other waste management programs.
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