Calculation of theM23magneto-optical absorption spectrum of ferromagnetic nickel

Abstract

The ${M}_{23}$ magneto-optical absorption spectrum of ferromagnetic nickel is calculated using an approach similar to the component state-density method that has been successfully used in obtaining valence-band emission and absorption x-ray spectra of metals. The ${M}_{23}$ magneto-optical effects result predominantly from spin-orbit splitting of the $3p$ core state in conjunction with the final $d$-state spin polarization. The calculated spectrum exhibits features that are directly related to electronic structure parameters including the $3p$ core spin-orbit splitting, and the unfilled $d$-band spin polarization. Temperature variations in the magneto-optical structure can be used to determine separately the exchange-splitting variation and spin-wave excitation contributions to the decrease in the magnetization. Experimental verification of these predictions should provide insight into the applicability of the Stoner model to ferromagnetic nickel and may be helpful in resolving some of the apparently conflicting results of other experimental probes of the spin polarization near the Fermi level in nickel.