Abstract
The dissociation energies of the CaF and UF molecules were calculated by a variational method. The electron density distribution in Ca+ was calculated for this purpose from the statistical model of the atom and on the Hartree-Fock approximation; the electron density in U+ was also calculated from the statistical model, on the basis of the author's earlier paper [1]. The electron density in the Ca+ ion was calculated on the Hartree-Fock principle. Both methods gave dissociation energies agreeing closely with experiment for the CaF. For UF there were no experimental data.
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