Calcium alginate-nZVI-biochar for removal of Pb/Zn/Cd in water: Insights into governing mechanisms and performance

Abstract

Heavy metals pollution in water caused by the intensification of industrial processes and human activities has attracted worldwide attention. Finding an environmental-friendly and efficient remediation method is in need. In this study, the calcium alginate entrapment and liquid-phase reduction method were used to prepare calcium alginate-nZVI-biochar composite (CANRC), which was firstly used to remove Pb2+, Zn2+, and Cd2+ in water. The effects of pyrolysis temperature, solution pH, and coexisting ions, etc. during adsorption processes were explored. Scanning electron microscope-Energy dispersive spectrometer (SEM-EDS), X-ray diffraction spectroscopy (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterize the physicochemical properties of CANRC before and after adsorption. Different adsorption models and site energy analysis were used to analyze the possible mechanisms. The results showed that CANRC prepared at 300 °C and a 5 wt% Fe loading ratio had the maximum adsorption capacities with a dosage of 2.5 g/L and pH = 5.0– 6.0. The adsorption process was more in line with the Langmuir isotherm model dominated by monolayer adsorption. The maximum adsorption capacities of Pb2+, Zn2+, and Cd2+ were 247.99, 71.77, and 47.27 mg/g, respectively. Site energy analysis combined with XRD and XPS analysis indicated that surface complexation and precipitation were the main adsorption mechanisms. This study provides an alternative way for the removal of heavy metals from water.