Abstract
Abstract Aldoses are rapidly epimerized at C-2 by combination of alkaline earth or rare earth metal ions (Ca2+, Sr2+, Pr3+, or Ce3+) and monoamines (triethylamine etc.). 13C NMR studies using [1-13C]-d-glucose of the Ca2+ system revealed that this reaction proceeds via the stereospecific rearrangement of carbon skeleton.
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