Busting the dust: Evaluating local vs distal sources in Quaternary sediments at Thirlmere Lakes

Abstract

The Quaternary sediments preserved within the Thirlmere Lakes system, Greater Blue Mountains World Heritage Area, Australia, are an important regional environmental record representing at least the last two interglacials. Understanding the source and evolution of these sediments, both temporally and spatially, is an essential component of the site's reconstruction. In this study, we evaluate this question using physical, mineralogical, elemental, and isotopic analytical techniques. Four distinct lake sediment facies all show bi-modal distributions of coarse sand and clay to fine silts, representing various mixtures of catchment Hawkesbury Sandstone and Ashfield Shale. Clays are predominantly kaolinite-dickite, however, the 7 Å dehydrated form of halloysite is prominent in an orange-yellow oxidised lake facies unit. The relative distribution and concentration of rare earth elements, including yttrium (REY), is heterogeneous across all the lake facies, varying between both lakes and with depth. This variability suggests a geochemical signature reflecting a combination of mixed sources and secondary mineral precipitation, driven by catchment geomorphology and specific site conditions. Slightly positive Ce anomalies in the oxidised lake facies, combined with the greater halloysite representation, represents a period of dry conditions and sub-aerial exposure. Evaluation of catchment, regional and continental REY ratios, Eu anomalies and εNd data implies a predominant internal catchment source signature, with any external contributions restricted to the local Bringelly Shale and the immediate south-eastern Australia, including the Murray River Basin. Geochemical and isotopic values for these proposed internal and external sediment sources predicts that an aeolian source from outside the immediate catchment represents a maximum of 30% of the fine-grained sediment fraction.